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r-LightBioCom achieves Milestone on the Development of new sustainable High-performance Composite Materials

r-LightBioCom - 1st Project Milestone achieved

In December 2023, the r-LightBioCom project has reached its first milestone identifying flax, hemp and basalt as well as recycled carbon fibres (r-CF), recycled glass fibres (r-GF) and recycled aramid fibres (r-Aramid) as sustainable fibres viable for project implementation. By reaching this milestone, the project has laid essential groundwork for the development of new high-performance composites for meeting the sustainability requirements of the project’s envisaged automotive, infrastructure and aeronautics use cases.

 

The r-LightBioCom project aims to develop new sustainable high-performance composites with inherent recyclability properties. In this context, the development and implementation of new raw materials that reduce weight and cost and introduce recyclability and sustainability to the resulting high-performance composites form the basis for all project results and the main advances in the state of the art. Therefore, the selection of sustainable fibres suitable for project implementation constitutes an essential building block of the project.

 

In close consultation with the use case owning project partners CRF (automotive use cases: spoiler and trunk floor), ACCIONA (infrastructure use case: composite pultruded profiles for tunnel lining) and ACITURRI (aeronautics use case: a vertical stabilizer panel), AITEX and HSKL reviewed and analysed appropriate fibres in terms of physical and mechanical properties and their processability into different textile intermediates for application in the respective use cases. Thoroughly evaluating various sustainable fibres, AITEX and HSKL identified two natural fibres, namely flax and hemp, one inorganic pristine fibre, namely basalt, and three recycled high-performance fibres, namely recycled carbon fibres, recycled glass fibres and recycle aramid fibres, as the most fitting choices for achieving the envisaged sustainability goals of the project’s use cases. Preliminary results of the LCA modelling carried out for these fibres by project partner CIDAUT confirm from an environmental point of view that the selected fibres are viable alternatives to conventional fibres.

Selected Natural Fibres Despite having lower mechanical properties compared to glass, carbon or basalt fibres, the use of natural fibres for sustainable high-performance composites is viable due to their positive impact on the environment during production, treatment and recycling at the end of the life cycle. Upon evaluating numerous natural fibres, bast fibres such as flax, hemp and kenaf turned out to have the best mechanical properties making them suitable for use as reinforcement in r-LightBioCom’s high-performance composites. Considering the carbon footprint associated with their production and transportation, flax and hemp have been selected as the most suitable options for the r-LightBioCom project.
r-LightBioCom Figure 1: Technical flax fibres used for non-wovens production
Figure 1: Technical flax fibres used for non-wovens production
Figure 2: Technical hemp fibres used for non-wovens production

Selected recycled High-performance Fibres

In the composites industry, a lot of technical fibre waste is generated at the end of products‘ life cycle. Since the recycling process has a smaller footprint than the process for obtaining pristine fibres, recycled carbon fibres, recycled glass fibres and recycled aramid fibres represent a sustainable solution in the framework of the r-LightBioCom project.

r-LightBioCom: Figure 3: Recycled carbon fibres used in r-LightBioCom
Figure 3: Recycled carbon fibres used in r-LightBioCom
Figure 4: Recycled glass fibres used in r-LightBioCom
Figure 4: Recycled glass fibres used in r-LightBioCom
r-LightBioCom Figure 5: Recycled aramid fibres used in r-LightBioCom
Figure 5: Recycled aramid fibres used in r-LightBioCom

In addition to the selected sustainable fibres, pristine carbon fibres[1] and pristine basalt fibres[2] have been chosen to meet specific mechanical requirements.[3] Further, blending recycled fibres with thermoplastic fibres resulted as necessity to reduce brittleness and improve the processability.[4]

 

To confirm the viability of the selected sustainable fibres for project implementation, textile intermediates were produced considering r-LightBioCom’s use case requirements. To this end, firstly different concentrations of natural, recycled and pristine fibres mixed with thermoplastic fibres were determined to meet mechanical performance and sustainability requirements, and subsequently, yarns, rovings, non-wovens and woven fabrics were manufactured.

 

Manufacturing non-wovens made from recycled carbon fibres with thermoplastic matrix show a good processability and good fibre dispersion. Challenges in the processability of recycled glass fibre, basalt and recycled aramid have been encountered, necessitating further refinement.

The ongoing tests utilizing bast and basalt fibre blends as reinforcement in polypropylene have shown promising initial results, indicating a significant enhancement in composite properties, particularly suitable for automotive applications.

r-LightBioCom Figure 6: Cross section of a non-woven made of 50% recycled carbon fibres - 50% Polypropylene ref
Figure 6: Cross section of a non-woven made of 50% recycled carbon fibres - 50% polypropylene ref (PP-ref)
r-LightBioCom Figure 7: Non-woven made from recycled glass fibres and polypropylene (PA6)
Figure 7: Non-woven made from recycled glass fibres and polypropylene reference (PP-ref)
r-LightBioCom Figure 8: Process of the obtention of non-woven and a veil made of 50% PA6 - 40% recycled carbon fibres - 10% pristine basalt fibres
Figure 8: Process of the obtention of non-woven and a veil made of 50% PA6 - 40% recycled carbon fibres - 10% pristine basalt fibres
r-LightBioCom Figure 9: Non-woven from bast fibre and thermoplastic
Figure 9: Non-woven from bast fibre and thermoplastic

Addressing the manufacturing of rovings for pultrusion suitable for the infrastructure application, a successful hybridization of recycled fibre rovings with pristine filaments has led to notable improvements in mechanical properties.

r-LightBioCom Figure 10: Different configurations of recycled aramid and basalt rovings
Figure 10: Different configurations of recycled aramid and basalt rovings
r-LightBioCom Figure 11: 3600 Tex roving for pultrusion
Figure 11: 3600 Tex roving for pultrusion

In the manufacturing of yarns and fabrics, a sizing application has proven essential to prevent brittleness in recycled carbon fibres during the weaving process. Hybridization of the recycled carbon fibre fabric has been proposed to elevate mechanical properties to meet the stringent requirements of the aeronautics applications.

r-LightBioCom Figure 12: Recycled carbon fibre + polypropylene (PA6) yarn obtained by retwisting
Figure 12: Recycled carbon fibre + polyamide (PA6) yarn obtained by retwisting
r-LightBioCom Figure 13: Recycled carbon fibre + polypropylene (PA6) fabric
Figure 13: Recycled carbon fibre + polyamide (PA6) fabric

In conclusion, the carefully selected sustainable fibres proposed for the r-LightBioCom project align with sustainability objectives, as they are of natural and recycled origins. The blends not only meet processability and dispersion requirements for textile intermediates, but also offer potential enhancements through hybridization, particularly in demanding use cases. This represents a significant step forward in the pursuit of sustainable high-performance composites.

For questions and further information about the achievements described in the article above, please contact:
Info-r-LightBioCom@dlr.de

[1] Pristine carbon fibres offer very high tensile strength, high stiffness and low density, which make them suitable for hybridization in recycled yarns and textiles.

[2] Basalt fibres have relatively low environmental impact while offering high mechanical properties. This makes pristine basalt fibres suitable for use as a pristine filament for recycled fibre rovings and chopped fibre for non-wovens

[3] In order to meet high mechanical requirements of applications (e.g. in the aeronautics application), the hybridization of rovings, yarns and fabrics made from recycled fibres with pristine carbon and pristine basalt fibres is being considered.

[4] Due to high brittleness and extreme fineness (5-15 µm), the selected recycled fibres require blending with thermoplastic fibres to enhance their compatibility and processability, e.g. by carding technology. For the r-LightBioCom project Polyamide (PA6), Polypropylene reference (PP-ref) and Polypropylene Malehic Anhydride (PP-MAH) have been selected.

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